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1 article(s) from Heber, Ulrich

Synthesis and structure of tricarbonyl(η⁶-arene)chromium complexes of phenyl and benzyl D-glycopyranosides

Thomas Ziegler and
Ulrich Heber

Beilstein J. Org. Chem. 2012, 8, 1059–1070, doi:10.3762/bjoc.8.118

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Figure 1: Known types of η⁶-tricarbonylchromium complexes of sugar derivatives [9-13].

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Scheme 1: Synthesis of glucoside 1l.

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Scheme 2: Deprotection of 2c and enzymatic cleavage of 3.

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Figure 2: ORTEP-plot of the asymmetric unit containing two molecules of compound 2a showing 30% probability e...

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Figure 3: ORTEP-plot of the asymmetric unit showing two molecules of compound 2b and 30% probability ellipsoi...

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Figure 4: ORTEP-plot of the asymmetrical unit showing two molecules of compound 2c and 30% probability ellips...

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Figure 5: ORTEP-plot of the asymmetric unit showing two molecules of compound 2d and 30% probability ellipsoi...

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Figure 6: ORTEP-plot of the asymmetrical unit showing two molecules of compound 2e and 30% probability ellips...

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Figure 7: ORTEP-plot of the asymmetric unit showing three molecules of compound 2j and 30% probability ellips...

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Figure 8: ORTEP-plot of the asymmetric unit showing three molecules of compound 2k and 30% probability ellips...

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Figure 9: ORTEP-plot of the asymmetric unit showing two molecules of compound pR-2m and 30% probability ellip...

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Figure 10: ORTEP-plot of the asymmetric unit showing three molecules of compound pS-2m and 30% probability ell...

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Published 11 Jul 2012

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Synthesis and structure of tricarbonyl(η6-arene)chromium complexes of phenyl and benzyl D-glycopyranosides

Synthesis and structure of tricarbonyl(η⁶-arene)chromium complexes of phenyl and benzyl D-glycopyranosides